Einstein’s Photo Electric Equation and Applications

Einstein’s photo electric equation explains photo electric effect and its further properties successfully. Wave theory of light has failed to explain concept of photo electric effect. Hence plank’s quantum concept is taken into consideration to explain this property. According to this property light is emitted by a source not continuously but discreetly in the form of wave packets called quanta.

When the light strikes a surface, number of photons are striking the surface. More the intensity, more the number of photons. Each photon will have certain energy, basing on the frequency of incident light. Each photon will pass all its energy to a electron on the surface of the metal. They electron is associated with the metal and it needs some energy to release itself from the valency orbit.

When the energy given by the photon is sufficient to release the electron from the metal surface, the electrons are emitted from the metal surface. The number of the electrons emitted from the metal surface depends on the number of the photons that are striking the metal surface. If the intensity of the light is more, there is availability of more number of photons and hence more photo electric current is emitted. That is the reason why intensity and the photo electric current are proportional to each other.

The electrons in the valency orbit need a minimum energy to get released itself from the metal surface. The incident frequency shall be able to give at least this much of energy to release the electron. This minimum frequency is called threshold frequency. This minimum required energy for the release of the electron is called work function. The energy given by the photon is first used to release the electron from the metal surface. If there is any further energy that is given by the photon, the electron uses that energy and moves with the kinetic energy.

According to photo electric equation, the entire energy supplied by the photon is used first to release the electron from the metal surface and then to move the electron from the cathode towards the anode. First the energy has to be supplied to release the electron from the metal surface and only when there is an extra energy it can be used to move the electron. Supplying of energy equal to work function is the precondition for the emission of photo electrons.

We can derive the equation for the maximum kinetic energy of by a electron as shown below.



If intensity of light is more, more photons are available and each photon will go and give its energy to the electrons. And hence there is more electrons emitted and hence there will be more photo electric current. The number of the electrons emitted is independent of frequency. But whether the current is able to be emitted are not is a dependent of frequency. The incident frequency and its corresponding energy shall be sufficient to release the electron from the metal surface. That is the energy of the frequency shall be more than the work function for the photo electric effect to happen.

Application

A monochromatic radiation incident on a metal surface of work function W, maximum kinetic energy of the emitted electrons is K. If the frequency of the incident radiation is n times the initial frequency and then how its kinetic energy will be affected?

We can write photo electric equation to solve this problem. We know that the total energy of the photon is equal to the sum of work function and the kinetic energy of the electron. Basing on that, we can write the equation for the kinetic energy in both the cases with their respective frequencies as shown below. Simply buy solving this to equations we can get the answer.




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Photo Electric Effect Experimental Observations

When a light of suitable frequency incident on a metal surface, electrons are emitted from the metal surface and these electrons are called photo electrons. The corresponding current is called photo electric current and the phenomena is called photo electric effect.

Photo electric effect is possible with any of the metal surface when the light of suitable frequency is allowed to incident on the metal surface. The incident frequency shall have a minimum value for this photo electric effect to happen and the minimum frequency is called the threshold frequency. When the incident frequency is more than threshold frequency, photo electric effect can happen.

We can express the threshold value even in terms of wavelength. Being frequency is reciprocal to wave length; threshold wavelength is the maximum wavelength of the light that is allowed to incident on a metal surface therefore photo electrons can be emitted. It means when the incident light is having a wavelength less than the threshold wavelength, photo electric effect is possible.

To observe the properties of photo electric effect , experimental arrangement is made as shown below. The apparatus consists of a discharge due with the cathode and anode. Light is allowed to incident on the cathode. The anode is further connected to a rheostat and then further to input a voltage.

When the incident frequency is more than threshold frequency, from the cathode photo electrons are emitted and the emitted photo electric current is measured with the ammeter connected in the circuit.

It is noticed that the photo electric effect is instantaneous process. It means immediately after the striking of light, photo electrons are emitted. There is no time lag in between .

When the voltage is not applied, the photo electrons are not having enough energy to continue travelling in the circuit and to make a consistent current. The applied voltage is enabling the flow of the current through the circuit.

When no voltage is applied, the released electrons get struck between the cathode and anode and they are called stacked electrons. These electrons further oppose the flow of the current and to overcome it, we need to apply the voltage. With the applied voltage, we can notice a steady flow of current in the circuit.



It is experimentally observed that, with the increase of intensity of light, the corresponding photo electric current is also increasing. The graph drawn between intensity of the light in the photo electric current is a straight line passing through the origin.

When the positive plate of the battery is connected to the anode and the negative plate is connected to cathode, there is an increase in the photo electric current. If reverse voltage is applied to the cathode, that is connecting a positive plate to the cathode, it is practically noticed that with the increase of voltage, photo electric current starts decreasing.

At a particular reverse voltage, photo electric current becomes zero and this particular voltage is called stopping potential. At the stopping potential the kinetic energy of the electrons is compensated by the potential energy acquired by the electron due to the stopping potential. We can equate both the energies basing on the law conservation of energy.

It is also practically noticed that stopping potential is independent of intensity of light. With different intensity of light, there may be different photo electric currents. But for all the intensities, stopping potentially is same. It is represented on the negative x-axis of the graph. On this graph voltage is taken on x-axis and the photo electric current is taken and y-axis.



It is also practically noticed that, stopping potentially is a dependent of frequency of the incident light. It is noticeable that for different frequencies of incident light, the corresponding stopping potentially is different. It is also experimentally observed that change of the frequency of the incident light is not going to affect the saturation current that is generated.

It is experimentally observed that higher the incident frequency, more the stopping potential.



We can draw a graph taking the incident frequency on x-axis and the stopping potential on y-axis. The graph is as shown below. It is observed that the incident frequency shall be more than threshold frequency for the photo electric current to emit. Then only we can apply reverse voltage so that somewhere in the photo electric current stops. Once if the applied frequency is more than the threshold frequency, it is observed that with the increase of frequency, the stopping potential also increases.





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